Thermodynamic and Kinetic Study on the Catalysis of  Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor

Dong, Wanglai; Chen, Lei; Yan, Hanzhao; Zhang, Zijie; Zhou, Zheng

Wanglai Dong, Lei Chen, Hanzhao Yan, Zijie Zhang, Zheng Zhou

Thermodynamic and Kinetic Study on the Catalysis of Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor

Abstract:

Esterification Thermodynamic and Kinetic on acetic acid with camphene was studied systematically in an intensified fixed bed reactor at 303-323 K with anhydrous NKC-9 resin. The catalyst loading, initial molar ratio, temperature, and catalyst reusability were studied and optimized. The method of UNIFAC was applied to calculate the activity coefficient of each component for correcting the nonideality of the solution. Reaction enthalpy, entropy, and Gibbs free energy were calculated. The kinetics of camphene esterification was studied by pseudo-homogeneous model (PH model), and the fitting effect was good, which provided experimental reference and theoretical basis for the industrial production of isobornyl acetate.

Keywords:
esterificationCcation exchange resinCthermodynamicsCkinetics

Issue: 2021, Volume 72, Issue 1

Pages: 111-124

Publication date: 2021/2/3

https://doi.org/10.37358/RC.21.1.8408

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
DONG, W., CHEN, L., YAN, H., ZHANG, Z., ZHOU, Z., Thermodynamic and Kinetic Study on the Catalysis of Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor, Rev. Chim., 72(1), 2021, 111-124.

Vancouver
Dong W, Chen L, Yan H, Zhang Z, Zhou Z. Thermodynamic and Kinetic Study on the Catalysis of Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor. Rev. Chim.[internet]. 2021 Jan;72(1):111-124. Available from: https://doi.org/10.37358/RC.21.1.8408

APA 6th edition
Dong, W., Chen, L., Yan, H., Zhang, Z. & Zhou, Z. (2021). Thermodynamic and Kinetic Study on the Catalysis of Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor. Revista de Chimie, 72(1), 111-124. https://doi.org/10.37358/RC.21.1.8408

Harvard
Dong, W., Chen, L., Yan, H., Zhang, Z., Zhou, Z. (2021). 'Thermodynamic and Kinetic Study on the Catalysis of Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor', Revista de Chimie, 72(1), pp. 111-124. https://doi.org/10.37358/RC.21.1.8408

IEEE
W. Dong, L. Chen, H. Yan, Z. Zhang, Z. Zhou, "Thermodynamic and Kinetic Study on the Catalysis of Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor". Revista de Chimie, vol. 72, no. 1, pp. 111-124, 2021. [online]. https://doi.org/10.37358/RC.21.1.8408

Text
Wanglai Dong, Lei Chen, Hanzhao Yan, Zijie Zhang, Zheng Zhou,
Thermodynamic and Kinetic Study on the Catalysis of Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor,
Revista de Chimie,
Volume 72, Issue 1,
2021,
Pages 111-124,
ISSN 2668-8212,
https://doi.org/10.37358/RC.21.1.8408.
(https://revistadechimie.ro/Articles.asp?ID=8408)
Keywords: esterificationCcation exchange resinCthermodynamicsCkinetics

RIS
TY - JOUR
T1 - Thermodynamic and Kinetic Study on the Catalysis of Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor
A1 - Dong, Wanglai
A2 - Chen, Lei
A3 - Yan, Hanzhao
A4 - Zhang, Zijie
A5 - Zhou, Zheng
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2021
VL - 72
IS - 1
SP - 111
EP - 124
UR - https://doi.org/10.37358/RC.21.1.8408
KW - esterificationCcation exchange resinCthermodynamicsCkinetics
ER -

BibTex
@article{RevCh2021P111,
author = {Dong Wanglai and Chen Lei and Yan Hanzhao and Zhang Zijie and Zhou Zheng},
title = {Thermodynamic and Kinetic Study on the Catalysis of Isobornyl Acetate by a Cation Exchange Resin an Intensified Fixed-Bed Reactor},
journal = {Revista de Chimie},
volume = {72},
number = {1},
pages = {111-124},
year = {2021},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.21.1.8408},
url = {https://revistadechimie.ro/Articles.asp?ID=8408}
}

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