Spectral Studies on Pt(II) and Pd(II) Complexes with N-benzoyl-N’-aryl Thiourea derivatives

Cîrcu, Viorel; Rosu, Tudor; Udrea, Silvia; Dumitrascu, Florea

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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2008, Volume 59, Issue 8,

https://doi.org/10.37358/RC.08.8.1923

Viorel Cîrcu, Tudor Rosu, Silvia Udrea, Florea Dumitrascu

Spectral Studies on Pt(II) and Pd(II) Complexes with N-benzoyl-N’-aryl Thiourea derivatives

Abstract:

A series of Pt(II) and Pd(II) complexes with N-benzoyl-N’-aryl thiourea derivatives were prepared and investigated by mean of several spectroscopic techniques: IR and UV-VIS, 1H and 13C NMR spectroscopy. These derivatives act as monodentate ligands through the sulphur atom to Pt(II) and as bidentate through the sulphur and oxygen atoms to Pd(II). The 1H NMR spectroscopy shows the presence of a mixture of cis and trans isomers in solution for both Pt(II) and Pd(II) complexes.

Keywords:
Pt(II) and Pd(II) complexes; N-benzoyl-N’-aryl thiourea; IR and UV-VIS; 1H and 13C NMR spectroscopy

Issue: 2008, Volume 59, Issue 8

Pages:

Publication date: 2008/9/9

https://doi.org/10.37358/RC.08.8.1923

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Viorel Cîrcu, Tudor Rosu, Silvia Udrea, Florea Dumitrascu Spectral Studies on Pt(II) and Pd(II) Complexes with N-benzoyl-N’-aryl Thiourea derivatives

Viorel Cîrcu, Tudor Rosu, Silvia Udrea, Florea Dumitrascu

Spectral Studies on Pt(II) and Pd(II) Complexes with N-benzoyl-N’-aryl Thiourea derivatives