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REVISTA DE CHIMIE
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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2003, Volume 54, Issue 1,





2-Chloroethylphosphonic Acids Grafted on Styrene-Divinylbenzene Copolymers through N-g-aminoethyl-aminomethyl, N-d-aminopropyl-aminomethyl, N-b-aminobutyl-aminomethyl Type Linkages

Adriana Popa, Corneliu-Mircea Davidescu

Abstract:

Synthesis of phosphonic acids grafted on copolymers with spacer-chain is described. Spacer-modified supports containing N-b-aminoethyl-aminomethyl, N-g-aminopropyl-aminomethyl and N-d-aminobuthyl-aminomethyl linkages were prepared by alkylation polymer-analogous reactions. The method is applied, extended and optimised for gel-type styrene-divinylbenzene copolymers with „5' and „7' degree of crosslinking. Keywords: polymer-supported phosphonic acid, chloromethylated styrene-divinylbenzene copolymer, spacer-modified copolymer

Issue: 2003, Volume 54, Issue 1
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