Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study

Iram, Shamaila; Imran, Muhammad; Kanwal, Farah; Latif, Shoomaila; Iqbal, Zafar

Shamaila Iram, Muhammad Imran, Farah Kanwal, Shoomaila Latif, Zafar Iqbal

Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study

Abstract:

Two Lead based organic frameworks (1 & 2) have been synthesized using 4,6-dihydroxy-2-mercaptopyrimidine (H2DMP) as organic linker. Lead nitrate (1) and Lead acetate (2) salts were used to investigate their influence on morphology of resulting MOFs, adsorption capacities and luminescence behaviour. Structure and morphology of these MOFs was established on the basis of UV/Vis, Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), 1H NMR, energy dispersive spectroscopy (EDS), thermogravimetric analysis (TGA) and X-ray diffraction technique. Brunauer-Emmett-Teller (BET) studies revealed better N2 adsorption capacity for 1 (surface area 814 m2/g) when compared with 2 (surface area 196 m2/g). Photoluminescence behaviour of (1 & 2) was investigated in solid state at room temperature and has been attributed to metal-centred s®p transition.

Keywords:
Bidentate ligands; Lead; Luminescence; Metal organic frameworks

Issue: 2019, Volume 70, Issue 10

Pages: 3545-3548

Publication date: 2019/11/15

https://doi.org/10.37358/RC.19.10.7593

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This article is published under the Creative Commons Attribution 4.0 International License

Citation Styles

Cite this article as:
IRAM, S., IMRAN, M., KANWAL, F., LATIF, S., IQBAL, Z., Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study, Rev. Chim., 70(10), 2019, 3545-3548.

Vancouver
Iram S, Imran M, Kanwal F, Latif S, Iqbal Z. Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study. Rev. Chim.[internet]. 2019 Oct;70(10):3545-3548. Available from: https://doi.org/10.37358/RC.19.10.7593

APA 6th edition
Iram, S., Imran, M., Kanwal, F., Latif, S. & Iqbal, Z. (2019). Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study. Revista de Chimie, 70(10), 3545-3548. https://doi.org/10.37358/RC.19.10.7593

Harvard
Iram, S., Imran, M., Kanwal, F., Latif, S., Iqbal, Z. (2019). 'Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study', Revista de Chimie, 70(10), pp. 3545-3548. https://doi.org/10.37358/RC.19.10.7593

IEEE
S. Iram, M. Imran, F. Kanwal, S. Latif, Z. Iqbal, "Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study". Revista de Chimie, vol. 70, no. 10, pp. 3545-3548, 2019. [online]. https://doi.org/10.37358/RC.19.10.7593

Text
Shamaila Iram, Muhammad Imran, Farah Kanwal, Shoomaila Latif, Zafar Iqbal,
Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study,
Revista de Chimie,
Volume 70, Issue 10,
2019,
Pages 3545-3548,
ISSN 2668-8212,
https://doi.org/10.37358/RC.19.10.7593.
(https://revistadechimie.ro/Articles.asp?ID=7593)
Keywords: Bidentate ligands; Lead; Luminescence; Metal organic frameworks

RIS
TY - JOUR
T1 - Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study
A1 - Iram, Shamaila
A2 - Imran, Muhammad
A3 - Kanwal, Farah
A4 - Latif, Shoomaila
A5 - Iqbal, Zafar
JF - Revista de Chimie
JO - Rev. Chim.
PB - Revista de Chimie SRL
SN - 2668-8212
Y1 - 2019
VL - 70
IS - 10
SP - 3545
EP - 3548
UR - https://doi.org/10.37358/RC.19.10.7593
KW - Bidentate ligands
KW - Lead
KW - Luminescence
KW - Metal organic frameworks
ER -

BibTex
@article{RevCh2019P3545,
author = {Iram Shamaila and Imran Muhammad and Kanwal Farah and Latif Shoomaila and Iqbal Zafar},
title = {Lead Based Metal Organic Frameworks(Pb-MOFs): Anion Influence, Luminescence and Gas Adsorption Study},
journal = {Revista de Chimie},
volume = {70},
number = {10},
pages = {3545-3548},
year = {2019},
issn = {2668-8212},
doi = {https://doi.org/10.37358/RC.19.10.7593},
url = {https://revistadechimie.ro/Articles.asp?ID=7593}
}

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