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REVISTA DE CHIMIE
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https://doi.org/10.37358/Rev.Chim.1949

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Revista de Chimie (Rev. Chim.), Year 2010, Volume 61, Issue 7,





Ilie SIMINICEANU, Natalia MARCHITAN, Gheorghe DUCA, Aliona Mereuta
Mathematical Models Based on Thermodynamic Equilibrium
and Kinetics of an Ion Exchange Process

Abstract:

A new adsorbent has been prepared from Amberlite IRA- 67 impregnated with the liquid ion- exchanger Amberlite LA-2 dissolved in n- hexane to recover tartaric acid (TA) from aqueous solution. The experiments done on a batch equipment proved the effectiveness of the new material: the separation degree of TA was100% in a contact time less than 30 minutes for the following values of the 6 main factors: solid/ liquid loading ] 1 g/L, T= 294 K, initial pH 2.5, initial TA concentration ]1 g/L, particle diameter 0.4- 1.2 mm, stirring 200 min-1. The equilibrium qe- ce data were better correlated through the Langmuir model (R2= 0.9962) compared to the Freundlich one (R2= 0.8535). The kinetic curves q- t have been confronted with 4 kinetic models, and the corresponding kinetic constants have been identified. The final conclusion was that, under the investigated conditions, the slowest step of the process was the intraparticle diffusion. Keywords: Freundlich, Langmuir, kinetic models, Lagergren, Ho- McKay, Weber- Morris, Dumwald- Wagner

Issue: 2010, Volume 61, Issue 7
Pages:
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